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Synthesis of Apoptolidinone

✍ Scribed by Julia Schuppan; Hermut Wehlan; Sonja Keiper; Ulrich Koert

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 102 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20010601)40:11<2063::aid-anie2063>3.0.co;2-#

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✦ Synopsis

A Cu -mediated coupling of the northern and southern units and a ring-size selective macrolactonization are the key steps in the convergent, first total synthesis of apoptolidinone, the aglycon of the potential antitumor compound apoptolidin. (The wavey lines in the picture are the retrosynthetic disconnections.).

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