Synthesis of and asymmetric induction by chiral bicyclic thiazolium salts
β Scribed by Roland L. Knight; Finian J. Leeper
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 212 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Polycyclic thiazoles, 6a and b, have been synthesised and the enantiomers resolved. Alkylation gave chiral thiazolium salts which catalyse the dimerisation of benzaldehyde to give benzoin with enantiomefic excesses up to 26%. Reasons for these results are discussed.
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