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Synthesis of Analogues of Eunicea γ-Cembranolides Containing Cyclic Ethers via Saponification †

✍ Scribed by Rodríguez, Abimael D.; Piña, Ivette C.; Acosta, Ana L.; Ramírez, Catherine; Soto, Javier J.

Book ID
126972972
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
180 KB
Volume
66
Category
Article
ISSN
0022-3263

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The Lewis acid mediated cyclization of y-oxygen substituted allylic stannane 1, having a chiral imine group at the terminus of the carbon chain, afforded trans ~amino cyclic ether 2 with very high to good diastereoselectivities in high chemical yields.