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Synthesis of an amphiphilic aldehyde using as a key step the condensation of a lipophilic glyoxylic acid amide derivative with tris(hydroxymethyl)aminomethane

✍ Scribed by Dominique Bonnet; Pascal Joly; Hélène Gras-Masse; Oleg Melnyk

Book ID
104230117
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
83 KB
Volume
42
Category
Article
ISSN
0040-4039

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Synthesis of an amphiphilic aldehyde usi
Synthesis of an amphiphilic aldehyde using as a key step the condensation of a lipophilic glyoxylic acid amide derivative with tris(hydroxymethyl)aminomethane
✍ Dominique Bonnet; Pascal Joly; Hélène Gras-Masse; Oleg Melnyk 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 83 KB

Spontaneous condensation of a glyoxylic acid amide derivative incorporating a palmitoyl group with tris(hydroxymethyl)aminomethane followed by Dess-Martin oxidation led to an heterocyclic amphiphilic aldehyde, which was successfully engaged in hydrazone formation in partial aqueous media.