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Synthesis of amino derivatives of caranol by the addition of cyclic amines to 3-carene oxides

✍ Scribed by I. V. Fedyunina; V. V. Plemenkov; G. Sh. Bikbulatova; L. E. Nikitina; I. A. Litvinov; O. N. Kataeva


Book ID
104851185
Publisher
Springer
Year
1992
Tongue
English
Weight
365 KB
Volume
28
Category
Article
ISSN
0009-3130

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A (+)-3-carene derived aminoalcohol was successfully used as a chiral ligand in the catalytic enantioselective diethylzinc addition to various aldehydes. Very high enantiomeric excess (up 98% in 1-(2-methoxyphenyl)-1-propanol) was obtained. A plausible mechanism has been suggested for the observed e