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Synthesis of Amines by the Intermolecular Schmidt Reaction of Aliphatic Azides with Carbocations

✍ Scribed by Pearson, William H.; Fang, Wen-kui


Book ID
125885624
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
239 KB
Volume
60
Category
Article
ISSN
0022-3263

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## Abstract An efficient one‐pot synthesis of sterically hindered aromatic tertiary amines through Lewis acid induced intermolecular Schmidt reaction of benzylic azides is described. In the presence of EtAlCl~2~, benzylic azide underwent a smooth Schmidt reaction to give the corresponding iminium i