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Synthesis of allyl sulfides via a palladium mediated allylation

โœ Scribed by Barry M Trost; Thomas S Scanlan

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
248 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A mild chemo-, regio-, and diastereoselective substitution of ally1 carbonates and vinyl epoxides by sulfur nucleophiles catalyzed by palladium can overcome difficulties in and complement conventional displacement without poisoning of the catalyst.

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Synthesis of protected allylic amines via palladium(0)-catalyzed amination of allylic acetates
โœ Nilantha S. Sirisoma; Patrick M. Woster ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 188 KB

Synthesis of potential antiparisitic 5'-aminonucloesides such as 10 could not be accomplished using standard amination procedures. Palladium(0)-catalyzed amination of cyclic allylic acetates with benzylamine or phthalimide gave the corresponding protected amines. This method was then extended to the