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Synthesis of Allenylidene Lithium and Silver Complexes, and Subsequent Transmetalation Reactions

✍ Scribed by Matt Asay; Bruno Donnadieu; Wolfgang W. Schoeller; Guy Bertrand

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
328 KB
Volume
121
Category
Article
ISSN
0044-8249

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Synthesis of Allenylidene Lithium and Si
Synthesis of Allenylidene Lithium and Silver Complexes, and Subsequent Transmetalation Reactions
✍ Matt Asay; Bruno Donnadieu; Wolfgang W. Schoeller; Guy Bertrand 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 329 KB 👁 2 views

## Abstract **Alpha, beta, gamma!** Amino substituents in alpha and beta positions allow the isolation of free carbenes, but even in the gamma position, their strong π‐electron‐donating properties permit the synthesis of allenylidene lithium adducts and silver complexes (see picture), which are ide