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Synthesis and Reactions of Lithium Chloromethyldimethylsilanolate

✍ Scribed by Dr. M. Wieber; Dr. C. D. Frohning

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
92 KB
Volume
5
Category
Article
ISSN
0044-8249

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## Abstract **Alpha, beta, gamma!** Amino substituents in alpha and beta positions allow the isolation of free carbenes, but even in the gamma position, their strong π‐electron‐donating properties permit the synthesis of allenylidene lithium adducts and silver complexes (see picture), which are ide