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Synthesis of Alkynes from Enol Esters

✍ Scribed by Prof. J. Cymerman Craig; Dr. M. D. Bergenthal; Dr. I. Fleming; Dr. J. Harley-Mason

Publisher: John Wiley and Sons
Year: 1969
Tongue: English
Weight: 853 KB
Volume: 8
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.196904291

No coin nor oath required. For personal study only.

✦ Synopsis

Eliminations leading from enol sulfonates, enol phosphates, and enol phosphonium salts to alkynes are reviewed. Olefin eliminations are usually the rate-determining step in the formation of the triple bond. Enol esters may also play a role in the biosynthesis of alkynes.

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