𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of alkylN-(α-amidomethyl)glycinates from glycine esters, aroylamides, and formaldehyde

✍ Scribed by S. G. Zlotin; I. V. Sharova; O. A. Luk'yanov

Book ID
112562145
Publisher
Springer
Year
1994
Tongue
English
Weight
236 KB
Volume
43
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Enantioselective synthesis of α-amino ac
Enantioselective synthesis of α-amino acids from glycine t-butyl ester
✍ Tsai-Lung Yeh; Chun-Chen Liao; Biing-Jiun Uang 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 656 KB

Enantioselective syntheses of optically active or-amino acids from glycine t-butyl ester through Schiff base employing (+)-N-alkyl-10-camphorsulfonamides as chiral auxiliaries were described. Methylation of Schiff base 5 gave high asymmetric inductions, whereas ethylation, allylation and benzylation

ChemInform Abstract: Enantioselective Sy
ChemInform Abstract: Enantioselective Synthesis of α-Amino Acids from Glycine t-Butyl Ester.
✍ T.-L. YEH; C.-C. LIAO; B.-J. UANG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

The diastereoselective synthesis of α-amino esters from the glycine ester (I) employing the sulfonamides (II) as chiral auxiliaries works well for α-alkylation with methyl iodide. Ethylation, allylation, and benzylation proceeds with fair stereoselectivity, but pure diastereomers can be obtained by