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Synthesis of alkene-substituted pentacyclo[5.4.0.02,6.33,10.05,9]undecanes. 2. Photoelectron spectra and electronic structures of substituted pentacyclo[5.4.0.02,6.03,10.05,9]undecanes

✍ Scribed by Marchand, Alan P.; Huang, Chunmin; Kaya, Riza; Baker, A. David; Jemmis, Eluvathingal D.; Dixon, David A.


Book ID
127164048
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
1007 KB
Volume
109
Category
Article
ISSN
0002-7863

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Thermodynamic rearrangement of the penta
✍ Kata MlinariΔ‡-Majerski; Jelena VeljkoviΔ‡; Alan P. Marchand; Bishwajit Ganguly πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 375 KB

Reaction of Pentaeyclo[5.4.0.02,6.03'10.05'9] undecmle-8,l l-dione (l) with ethanedithiol, when performed in the presence of a Lewis acid catalyst (F3B-OEt2), afforded the corresponding mono(ethylene dithioacetal), 2, along with 7,8-[(thicethano)thio]pentacyclo[6.3.0.02,6.03, lO.05,9]undecan-l 1-on