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Improved synthesis of pentacyclo[5.4.0.02,6.03,10.05,9]undecane

✍ Scribed by Marchand, Alan P.; Allen, Robert W.


Book ID
120605332
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
151 KB
Volume
39
Category
Article
ISSN
0022-3263

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Thermodynamic rearrangement of the penta
✍ Kata MlinariΔ‡-Majerski; Jelena VeljkoviΔ‡; Alan P. Marchand; Bishwajit Ganguly πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 375 KB

Reaction of Pentaeyclo[5.4.0.02,6.03'10.05'9] undecmle-8,l l-dione (l) with ethanedithiol, when performed in the presence of a Lewis acid catalyst (F3B-OEt2), afforded the corresponding mono(ethylene dithioacetal), 2, along with 7,8-[(thicethano)thio]pentacyclo[6.3.0.02,6.03, lO.05,9]undecan-l 1-on