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Synthesis of alkaloids from amino acids via N-acyliminium ions generated by one-pot radical decarboxylation–oxidation

✍ Scribed by Alicia Boto; Rosendo Hernández; Ernesto Suárez

Book ID: 104210151
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 121 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00306-3

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✦ Synopsis

A one-pot methodology for the synthesis of α-substituted nitrogen heterocycles from commercial amino acids has been developed. Good stereoselectivity can be achieved with chiral substituted rings. This procedure has been applied to the synthesis of piperidine, pyrrolidine and indolizidinone alkaloids.

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