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Synthesis of Alkaloid (−)-205B via Stereoselective Reductive Cross-Coupling and Intramolecular [3+2] Cycloaddition

✍ Scribed by Yang, Dexi; Micalizio, Glenn C.

Book ID
115458117
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
947 KB
Volume
134
Category
Article
ISSN
0002-7863

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A stereoselective synthesis of 3-substit
A stereoselective synthesis of 3-substituted hexahydroindeno[2,1-b]pyrroles via an intramolecular azomethine ylide cycloaddition
✍ John D. Harling; Barry S. Orlek 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 422 KB

3-Substituted hexahydroindeno[2,1-b]pyrroles were prepared in a stereoselective manner in high yield v/a an intramolecular azomethine ylide cycloaddition. Olefin geometry in the ylide precursor controlled the stereochemistry at the 3position.