## Abstract Aliphatic as well as aromatic acid chlorides are reduced smoothly into aldehydes at room temperature and atmospheric pressure by hydrogenation, using palladium on carbon as the catalyst, acetone or ethyl acetate as solvent and ethyldiisopropylamine as hydrogen chloride acceptor. The rea
โฆ LIBER โฆ
Synthesis of Aldehydes by Rosenmund Reduction
โ Scribed by Yadav, Vasanti G.; Chandalia, S. B.
- Book ID
- 121686422
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 367 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1083-6160
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We have found that-olefin-palladium chloride complex is carbonylated to give 8-chloro acyl chloride.\* In addition, ve have found that metallic palladium ia a versatile catalyst for carbonylation of various olefinic compounds. For example, simple olafins and nonconjugated cyuloolefins4 can be conver