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Organic Reactions || The Rosenmund Reduction of Acid Chlorides to Aldehydes

โœ Scribed by Mosettig, Erich


Book ID
120473165
Publisher
John Wiley & Sons, Inc.
Year
2011
Tongue
English
Weight
972 KB
Category
Article
ISBN-13
9780471264187

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## Abstract Aliphatic as well as aromatic acid chlorides are reduced smoothly into aldehydes at room temperature and atmospheric pressure by hydrogenation, using palladium on carbon as the catalyst, acetone or ethyl acetate as solvent and ethyldiisopropylamine as hydrogen chloride acceptor. The rea

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Chlorides of a variety of acids : primary, secondary, tertiary, long chain aliphatic and tx~-unsaturated have been converted into aldehydes by reduction with formic acid at pH 9-10 at room temperature in high 3ields.