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Reduction of acid chlorides to aldehydes by means of the hydridoirontetracarbonyl anion

โœ Scribed by T.E. Cole; R. Pettit


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
180 KB
Volume
18
Category
Article
ISSN
0040-4039

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## Abstract Aliphatic as well as aromatic acid chlorides are reduced smoothly into aldehydes at room temperature and atmospheric pressure by hydrogenation, using palladium on carbon as the catalyst, acetone or ethyl acetate as solvent and ethyldiisopropylamine as hydrogen chloride acceptor. The rea

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Chlorides of a variety of acids : primary, secondary, tertiary, long chain aliphatic and tx~-unsaturated have been converted into aldehydes by reduction with formic acid at pH 9-10 at room temperature in high 3ields.