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Synthesis of adamantane derivatives. XXXII. The Beckmann rearrangement and fragmentation aptitude of noradamantan-2-one oxime

โœ Scribed by Sasaki, Tadashi.; Eguchi, Shoji.; Hiroaki, Osamu.


Book ID
127209867
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
665 KB
Volume
41
Category
Article
ISSN
0022-3263

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ChemInform Abstract: The Beckmann Rearra
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The Beckmann Rearrangement of Cyclohex-2-enone Oximes. Synthesis of 4, 5-Diphenyl-2,3,4,5-tetrahydro-1H-azepin-2-one. -The title compound (VI), which is an intermediate for the preparation of certain pesticides, can be prepared from both isomeric oximes (IV) and (V). In contrast, only the syn oxime