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Synthesis of acetylenic γ -hydroxy aldehydes and their reaction with primary amines

✍ Scribed by A. S. Medvedeva; L. P. Safronova; G. G. Chichkareva; M. G. Voronkov

Book ID
112439327
Publisher
Springer
Year
1976
Tongue
English
Weight
280 KB
Volume
25
Category
Article
ISSN
1573-9171

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Highly Enantioselective Synthesis of γ-Hydroxy-α,β-acetylenic Esters by Asymmetric Alkyne Addition to Aldehydes
✍ Ge Gao; Qin Wang; Xiao-Qi Yu; Ru-Gang Xie; Lin Pu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB 👁 1 views

g-Hydroxy-a,b-acetylenic esters containing three adjacent and structurally very different functional groups are very useful in the synthesis of highly functionalized organic molecules. [1, 2] This class of compound is normally prepared by treatment of an alkyl propiolate with nBuLi at À78 8C