Synthesis of a Regiospecifically Fluorinated Polysaccharide 3-Deoxy-3-fluoro-(1→6)-α- d -glucopyranan via Ring-Opening Polymerization
✍ Scribed by Kobayashi, Kazukiyo; Kondo, Tatsuru
- Book ID
- 127012384
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 182 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0024-9297
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📜 SIMILAR VOLUMES
## Abstract Ring‐opening polymerization of a new anhydro‐hexose monomer having an azido group, 1,6‐anhydro‐3‐azido‐2,4‐di‐__O__‐benzyl‐3‐deoxy‐β‐D‐allopyranose (A3ABA), was carried out with Lewis acid catalysts to give a stereoregular (1→6)‐α‐D‐allopyranan derivative having the azido group at the C
## Abstract Ring‐opening polymerization of a new anhydro ribose‐type monomer, 1,4‐anhydro‐3‐azido‐3‐deoxy‐2‐__O‐tert__‐butyldimethylsilyl‐α‐D‐ribopyranose (A3ASR), was investigated. The monomer was synthesized from 1,4‐anhyro‐α‐D‐xylopyranose by three steps comprising Walden inversion at the C3 pos