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Chemical synthesis of (1→3)-β-D-glucopyranan by ring-opening polymerization of a 1,3-anhydro sugar derivative

✍ Scribed by Okada, Masahiko; Yamakawa, Yoshitaka; Sumitomo, Hiroshi


Book ID
127057807
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
392 KB
Volume
24
Category
Article
ISSN
0024-9297

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✍ Byoung Won Kang; Kazuyuki Hattori; Takashi Yoshida; Makoto Hirai; Yoon Soung Chi 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 648 KB

## Abstract Ring‐opening polymerization of a new anhydro ribose‐type monomer, 1,4‐anhydro‐3‐azido‐3‐deoxy‐2‐__O‐tert__‐butyldimethylsilyl‐α‐D‐ribopyranose (A3ASR), was investigated. The monomer was synthesized from 1,4‐anhyro‐α‐D‐xylopyranose by three steps comprising Walden inversion at the C3 pos