Synthesis of a perfluoroalkyl-substituted α-diimine by Sm-mediated reductive coupling
✍ Scribed by Joseph P. Sadighi; Lawrence M. Henling; Jay A. Labinger; John E. Bercaw
- Book ID
- 108284742
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 136 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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1,2,4-trithioles 2a-e are readily obtained in good yields by dimerization of benzoyldithioacetic acid derivatives using samarium diiodide as a promotor under very mild conditions. The structures of compounds 2a-e were determined by IR, 1 H, and 13 C NMR spectroscopies using heteronuclear multiple bo
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