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Enantioselective Reductive Coupling of 1,3-Enynes to Glyoxalates Mediated by Hydrogen: Asymmetric Synthesis of β,γ-Unsaturated α-Hydroxy Esters

✍ Scribed by Hong, Young-Taek; Cho, Chang-Woo; Skucas, Eduardas; Krische, Michael J.

Book ID
126418566
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
140 KB
Volume
9
Category
Article
ISSN
1523-7060

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✍ Young-Taek Hong; Chang-Woo Cho; Eduardas Skucas; Michael J. Krische 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

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g-Hydroxy-a,b-acetylenic esters containing three adjacent and structurally very different functional groups are very useful in the synthesis of highly functionalized organic molecules. [1, 2] This class of compound is normally prepared by treatment of an alkyl propiolate with nBuLi at À78 8C