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Synthesis of a Novel C2-Symmetric Thiourea and Its Application in the Pd-Catalyzed Cross-Coupling Reactions with Arenediazonium Salts under Aerobic Conditions

✍ Scribed by Dai, Mingji; Liang, Bo; Wang, Cuihua; Chen, Jiahua; Yang, Zhen

Book ID: 111900938
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 254 KB
Volume: 6
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol036182u

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## Abstract New, bulky __N__,__N__‐disubstituted acyclic and cyclic bis(thiourea) ligands have been designed and synthesized. Their palladium(0) complexes are very stable and are active catalysts for Heck and Suzuki coupling reactions of aryl iodides and bromides under aerobic conditions. Good TONs