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The Design and Synthesis of Bis(thiourea) Ligands and Their Application in Pd-Catalyzed Heck and Suzuki Reactions under Aerobic Conditions.

✍ Scribed by Wei Chen; Rui Li; Bo Han; Bang-Jing Li; Ying-Chun Chen; Yong Wu; Li-Sheng Ding; Dan Yang


Publisher
John Wiley and Sons
Year
2006
Weight
39 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract A novel __C__~2~ symmetrical and sterically bulky thiourea ligand **1** has been successfully applied to Heck, Suzuki and Suzuki‐type carbonylative coupling reactions under aerobic conditions. Since the metal‐sulfur bond in the thiourea complexes is stronger than the metal‐phosphorus bo