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Synthesis of a new family of water-soluble tertiary phosphine ligands and of their rhodium(I) complexes; olefin hydrogenation in aqueous and biphasic media

✍ Scribed by Eric Ranaud; Robert B. Russell; Suzanne Fortier; Stephen J. Brown; Michael C. Baird


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
890 KB
Volume
419
Category
Article
ISSN
0022-328X

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Chemistry in Environmentally Benign Medi
✍ Berning, Douglas E. ;Katti, Kattesh V. ;Barnes, Charles L. ;Volkert, Wynn A. πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 473 KB πŸ‘ 1 views

The reactions of water-soluble phosphanes P(CH,OH), (1) and Ph2PCH20H (2) with NaAuC14 in aqueous or alcoholic media, produced the water/alcoholic-soluble Au' complexes [Au(P(CH,OH),),]+ (3) and [Au(Ph2PCH20H):J+ (4) in near quantitative yields. The X-ray structures of 3 and 4, reported in this pape