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Synthesis of a highly functionalized tricyclic ring system related to guanacastepene via a tandem ring-closing metathesis reaction

✍ Scribed by François-Didier Boyer; Issam Hanna

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
153 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

A new approach to a highly functionalized 5,7,6-tricyclic core structure of guanacastepene has been developed using the tandem ring-closing metathesis reaction of dienynes as the key step.

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Total synthesis of octalactin A via ring
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✍ Keith R Buszek; Nagaaki Sato; Youngmee Jeong 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 93 KB

A new total synthesis of the novel lactone natural product octalactin A is described. The key step involves the facile construction of the eight-membered lactone core via ring-closing metathesis (RCM). This oxocene was elaborated to give the powerful antitumor agent octalactin A.

ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of Octalactin A via Ring-Closing Metathesis Reaction.
✍ Keith R. Buszek; Nagaaki Sato; Youngmee Jeong 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

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