𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of a hexose-analogue of prumycin (4-D-alanylamino-2-amino-2,4-dideoxy-d-galactopyranose)

✍ Scribed by Hiroyoshi Kuzuhara; Otoji Mori; Sakae Emoto

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
226 KB
Volume
17
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Total synthesis of 4-(d-alanylamino)-2-a
Total synthesis of 4-(d-alanylamino)-2-amino-2,3,4-trideoxy-dl-threo-pentose (3-deoxy-dl-prumycin)
✍ Violetta Constantinou-Kokotou; Elias A. Couladouros; Minas P. Georgiadis; George πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 726 KB

3-Deoxy-DL-prumycin (1) was synthesized from 2-furanmethanol (2-furfuryl alcohol, 2) in eleven steps in 15% total yield. Michael addition of azide anion to 2,3-dideoxy-oqent-2-enopyranos~ulose (3) and reduction in situ of the adduct afforded the key intermediates 5 and 6. Introduction of a second ax

A novel synthesis of 4-deoxy-d-lyxo-hexo
A novel synthesis of 4-deoxy-d-lyxo-hexose (β€œ4-deoxy-d-mannose”) from 1,6-anhydro-3,4-dideoxy-Ξ²-d-glycero-hex-3-enopyranose-2-ulose (levoglucosenone)
✍ Katsuya Matsumoto; Takashi Ebata; Koshi Koseki; Koji Okano; Hiroshi Kawakami; Ha πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 595 KB

Replacement of natural sugars by 4-deoxy-D-lyxo-hexose ("4-deoxy-D-mannose", 8) as the component parts of saccharides may endow compounds with new functions or biological activities. In previous studies, syntheses of 8 gave low overall yields or required many steps 1-4 Thus a simplified synthetic ro