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Synthesis of a family of epoxyvinyltriflate stereotetrads from 4-hydroxycyclohex-2-en-1-one

โœ Scribed by J.B. Evarts Jr.; P.L. Fuchs

Book ID
104261138
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
199 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

4-Hydroxy cylohex-2-en-l-one can be converted into a family of highly oxygenated cyclohexyl epoxyvinyltriflates by epoxidation, rearrangement, and epoxidation. Furthermore, double stereoselection via Jacobsen epoxidation enables synthesis of compounds such as 20a which were previously very difficult to prepare.

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ChemInform Abstract: Synthesis via Vinyl Sulfones. Part 79. Synthesis of a Family of Epoxyvinyltriflate Stereotetrads from 4-Hydroxycyclohex-2-en-1-one.
โœ J. B. Evarts Jr.; P. L. Fuchs ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Synthesis via Vinyl Sulfones. Part 79. Synthesis of a Family of Epoxyvinyltriflate Stereotetrads from 4-Hydroxycyclohex-2-en-1-one. -A strategy for the diastereoselective conversion of 4-hydroxycyclohex-2-en-1-one into tetraoxygenated cyclohexanone enol triflates of type (X) and (XI) is presented. T