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ChemInform Abstract: Synthesis via Vinyl Sulfones. Part 79. Synthesis of a Family of Epoxyvinyltriflate Stereotetrads from 4-Hydroxycyclohex-2-en-1-one.

✍ Scribed by J. B. Evarts Jr.; P. L. Fuchs

Book ID: 101880590
Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199926106

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✦ Synopsis

Synthesis via Vinyl Sulfones. Part 79. Synthesis of a Family of Epoxyvinyltriflate Stereotetrads from 4-Hydroxycyclohex-2-en-1-one. -A strategy for the diastereoselective conversion of 4-hydroxycyclohex-2-en-1-one into tetraoxygenated cyclohexanone enol triflates of type (X) and (XI) is presented. The route involves epoxidation, rearrangement, and a second epoxidation. -(EVARTS JR.,

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