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Synthesis of a chiral phosphine and a phosphinite from carbohydrates and application to asymmetrical hydrogenation

✍ Scribed by Manabu Yamada; Mitsuji Yamashita; Saburo Inokawa


Book ID
108308719
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
221 KB
Volume
95
Category
Article
ISSN
0008-6215

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Aminophosphine Phosphinites Derived from
✍ Rongliang Lou; Aiqiao Mi; Yaozhong Jiang; Yong Qin; Zhi Li; Fangmin Fu; Albert S 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 125 KB

AbstractÐA series of chiral aminophosphine phosphinites DPAMPPs was synthesized from optically active 1,2-diphenyl-2-aminoethanols. The erythro-DPAMPPs were found to serve as excellent ligands for rhodium-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives. For an array of dehydroami