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Synthesis of a carbocyclic analog of quercetin via a Barbier reaction

✍ Scribed by Neng-Yang Shih; Pietro Mangiaracina; Michael J. Green; Ashit K. Ganguly

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
231 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

A six-step synthetic route to the carbocyclic flavanoid 2 is described. The key step involves a 1,4-addition of a tertiary bromide to a a,&unsaturated ester by the Barbier reaction.

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