𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of a carba-sugar analog of trehalosamine, [(1S)-(1,2,43,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl] α-d-glucopyranoside, and a revised synthesis of its β anomer

✍ Scribed by Seiichiro Ogawa; Kenji Nishi; Yasushi Shibata


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
760 KB
Volume
206
Category
Article
ISSN
0008-6215

No coin nor oath required. For personal study only.

✦ Synopsis


Synthesis of a carba-sugar analog of trehalosamine, W9-(l2,4/3,W -amino-3,4-dihydroxy+hydroxymethyl-lcyclohexyl] a-D-glucopyranoside, and a revised synthesis of its j3 anomer*


📜 SIMILAR VOLUMES


Synthesis of [(1S)-(1,2,4/3,5)-2-amino-3
✍ Seiichiro Ogawa; Tatsuhi Toyokuni; Yoshio Hattori; Taisuke Nose; Tetsuo Suami 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 469 KB

As part of a study of the elucidation of biochemical and biological properties of pseudo-sugars', replacement of the hexopyranosyl residues of biologically active disaccharides with structurally related pseudo-sugars has been investigated. Trehalosamine\* (1) is an aminoglycoside antibiotic3 produce

Synthesis of 1d-(1,3,5/2,4)-4-acetamido-
✍ Lai-Xi Wang; Nobuo Sakairi; Hiroyoshi Kuzuhara 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 816 KB

The synthesis of the title compound and lo-(1,3,5/2,4)-4-acetamido-5-amino-3-O-( fl-o-glucopyranosyluronic acid)-l,2,3-cyclohexanetriol is described. Starting from methyl 2-acetamido-2-deoxy-a-o-glucopyranoside 2L-(2,4,5/3)-4-acetamido-3-benzoyloxy-2-benzyloxy-5 -hydroxycyclohexanone was prepared vi

2-Amino-8-(2-deoxy-2-fluoro-β-D-arabinof
✍ Virginie Glaçon; Frank Seela 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 German ⚖ 112 KB

## Abstract Nucleobase‐anion glycosylation of 2‐[(2‐methyl‐1‐oxopropyl)amino]imidazo[1,2‐__a__]‐1,3,5‐triazin‐4(8__H__)‐one (**6**) with 3,5‐di‐__O__‐benzoyl‐2‐deoxy‐2‐fluoro‐__α__‐D‐arabinofuranosyl bromide (**8**) furnishes a mixture of the benzoyl‐protected anomeric 2‐amino‐8‐(2‐deoxy‐2‐fluoro‐D

Synthesis of benzyl O-(2-O-methyl-β-d-ga
✍ Arun K. Sarkar; Rakesh K. Jain; Khushi L. Matta 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 1002 KB

Treatment of benzyl O-/?-n-galactopyranosyl-( 1+3)-2-acetamido-2-deoxy-4,6-O-isopropylidene-j3-D-glucopyranoside with tert-butylchlorodiphenylsiiane afforded the 6'-0-tert-butyldiphenylsilyl ether, which was converted into the 3',4'-0-isopropylidene derivative. Methylation and subsequent removal of