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Synthesis of a bis(diketiminate)bromosamarium(III) complex and its activity in the polymerization of methyl methacrylate

✍ Scribed by Roberto Bineli Muterle; Fabio Fabri; Regina Buffon; Wanda de Oliveira; Ulf Schuchardt


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
227 KB
Volume
317
Category
Article
ISSN
0926-860X

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Mechanism of polymerization of methyl me
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The triphenylphosphine (TPP) initiated polymerization of methyl methacrylate (MMA) in dimethyl sulphoxide (DMSO) has been studied. The polymerization was found to be solvent-sensitive and could be accelerated by Lewis acids like Fe 3Γ· . Kinetic studies showed that the propagation was free radical in