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Synthesis of 9-oxime-11,12-carbamate ketolides Through a novel N-deamination reaction of 11,12-hydrazonocarbamate ketolide

✍ Scribed by Alexis Denis; Jean-Marie Pejac; François Bretin; Alain Bonnefoy


Book ID
108479338
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
234 KB
Volume
11
Category
Article
ISSN
0968-0896

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## Abstract The novel, low‐melting‐point (19 °C) salt [__N__‐pentylpyridinium]^+^ [__closo__‐CB~11~H~12~]^−^ (2) was synthesized in 93% yield and characterized by elemental analysis, IR spectroscopy, and ^1^H, ^13^C, and ^11^B NMR spectroscopy. The salt was used as a solvent in several dehalogenati