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Synthesis of 9-Alkylidene-9 H -fluorenes by a Novel, Palladium-Catalyzed Cascade Reaction of Aryl Halides and 1-Aryl-1-alkynes

✍ Scribed by Larock, Richard C.; Tian, Qingping


Book ID
127106689
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
105 KB
Volume
66
Category
Article
ISSN
0022-3263

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## Abstract A novel method is reported for the synthesis of 9,9‐disubstituted 9__H__‐pyrrolo[1,2‐__a__]indoles. Cyclization of 1‐[2‐(1‐aryl(or methyl)ethenyl)phenyl]‐1__H__‐pyrroles, which can be easily prepared from 2‐(1‐aryl(or methyl)ethenyl)anilines, proceeds smoothly, in general, at 0Β° in the