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Synthesis of 6-Deoxy and 3,6-Dideoxy Derivatives from Unprotected Glycosides Employing the Mitsunobu Reaction

✍ Scribed by Dancy, Isabelle ;Laupichler, Lothar ;Rollin, Patrick ;Thiem, Joachim

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 861 KB
Volume: 1993
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199319930158

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✦ Synopsis

Abstract

Starting with unprotected hexopyranoside derivatives, an efficient synthesis of 6‐deoxy‐ and 3,6‐dideoxyhexopyranosides was achieved in two consecutive steps involving a highly regioselective Mitsunobu reaction and subsequent desulfurization.

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