Starting from sucrose, 2,3,1' ,3',4',6'-hexa-O-benzoyl-6-deoxy-6-iodosucrose\* (1) was synthesized. ## Reaction of 1 with sulfuryl chloride in pyridine gave 2,3,1 ',3',4',6'-hexa-O-benzoyl-4-chloro-4,6-dideoxy-6-iodogalactosucrose (2). Compound 2 was treated with tributyltin hydride in toluene i
Synthesis of 6-deoxy-6-fluorosucrose, and its inhibition of Leuconostoc and Streptococcusd-glucansucrases
β Scribed by Steven H. Eklund; John F. Robyt
- Book ID
- 102994717
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 414 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0008-6215
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π SIMILAR VOLUMES
A chemoenzymatic route to 6-deoxy (D-fructose 5b and L-sochose 5a) is described.This method is based on conversion of racemic 2.3-dihydroxybutyraldehyde to 5a and Sb catalyzed by spinach leaves Transketolase. Only the (R,R) and (R,S) isomers of 2,3-dihydroxybutymkiehyde react, yielding 6-deoxy-D-fmc
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v