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A convenient synthesis of 6-amino-6-deoxy- and 6-deoxy-d-glucopyranose

✍ Scribed by René Csuk


Book ID
107725512
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
131 KB
Volume
140
Category
Article
ISSN
0008-6215

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Chemoenzymatic synthesis of 6-deoxy-D-fr
✍ Laurence Hecquet; Jean Bolte; Colette Demuynck 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 514 KB

A chemoenzymatic route to 6-deoxy (D-fructose 5b and L-sochose 5a) is described.This method is based on conversion of racemic 2.3-dihydroxybutyraldehyde to 5a and Sb catalyzed by spinach leaves Transketolase. Only the (R,R) and (R,S) isomers of 2,3-dihydroxybutymkiehyde react, yielding 6-deoxy-D-fmc