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Synthesis of 5,6-carbonyldioxyindole, a melanogenic cyclic carbonate ester of 5,6-dihydroxyindole

โœ Scribed by Wilson B. Lutz; Craig R. Mcnamara; Max R. Olinger; David F. Schmidt; Douglas E. Doster; Mark D. Fiedler

Book ID
112127569
Publisher
Journal of Heterocyclic Chemistry
Year
1984
Tongue
English
Weight
416 KB
Volume
21
Category
Article
ISSN
0022-152X

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Synthesis of optically active tetrameric
Synthesis of optically active tetrameric melanin intermediates by oxidation of the melanogenic precursor 5,6-dihydroxyindole-2-carboxylic acid under biomimetic conditions
โœ Alessandro Pezzella; Davide Vogna; Giuseppe Prota ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 200 KB

In a recent work addressing the structural characterization of melanin pigments, we reported the isolation and characterization of trimeric oligomers of 5,6-dihydroxyindole-2-carboxylic acid (DHICA), a key intermediate in the biosynthesis of the dark brown eumelanins, by tyrosine catalyzed oxidation