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Synthesis of 5(10)-estrene-3,6,17-trione, an example of deconjugation of an α,β-unsaturated ketone

✍ Scribed by F. J. Zeelen; S. A. Szpilfogel


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
198 KB
Volume
83
Category
Article
ISSN
0165-0513

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Synthesis of 3α-hydroxy -5β,10β-epoxychi
✍ C. Harde; F. Bohlmann 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 677 KB

Starting with CI-methoxytetralone the unusual diterpene Sahydroxy-5&10,3-epoxychiliolide (l5a) has been synthesized vk methyl-[lcu,2a]-l',2,3,4,5,6,7,8-ocCahydro-6-oxo-l-g-propenyl)-~,5-trimethyl-1-naphthoate (9) which by boranate reduction gave the desired o-hydroxy derivative.-Oxidative degradatlo