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Synthesis of 5-Thio- l -fucose-Containing Disaccharides, as Sequence-Specific Inhibitors, and 2‘-Fucosyllactose, as a Substrate of α- l -Fucosidases †

✍ Scribed by Izumi, Masayuki; Tsuruta, Osamu; Harayama, Satoru; Hashimoto, Hironobu


Book ID
126063478
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
379 KB
Volume
62
Category
Article
ISSN
0022-3263

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## Abstract The __García‐González__ reaction of D‐glucose and ethyl acetoacetate generated ethyl 5‐[(1′__S__)‐D‐erythrosyl]‐2‐methyl‐3‐furoate (**5**), which was converted to ethyl 5‐[(1′__R__)‐1′,4′‐dideoxy‐1′,4′‐imino‐D‐erythrosyl]‐2‐methyl‐3‐furoate (**3c**) and to ethyl 5‐[(1′__S__)‐1′,4′‐dideo