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Synthesis of 5-membered cyclic carbonates by oxidative carbonylation of 1,2-diols promoted by copper halides

✍ Scribed by Giannoccaro, Potenzo; Casiello, Michele; Milella, Antonella; Monopoli, Antonio; Cotugno, Pietro; Nacci, Angelo


Book ID
119328587
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
627 KB
Volume
365
Category
Article
ISSN
1381-1169

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A General and Expedient Synthesis of 5-
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## Abstract We present a general, practical, and efficient approach to 5‐ and 6‐membered organic carbonates by palladium‐catalyzed direct oxidative carbonylation of 1,2‐ and 1,3‐diols, respectively. Reactions were carried out at 100 °C in __N__,__N__‐dimethylacetamide as the solvent under 20β€…atm (a