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Synthesis of 5-Fluoroalkylated Pyrimidine Nucleosides via Negishi Cross-Coupling

✍ Scribed by Chacko, Ann-Marie; Qu, Wenchao; Kung, Hank F.

Book ID
120358865
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
316 KB
Volume
73
Category
Article
ISSN
0022-3263

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Synthesis of 2',5'-Dideoxy-5'-Substituted Pyrimidine Nucleosides via Intramolecular Glycosylation. -5'-Azido and 5'-arylthio-5-deoxypyrimidine nucleosides are synthesized employing intramolecular glycosylation, in which a reaction intermediate is treated in situ with an azide salt or thiol. In some