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Synthesis of 5-bromopentanoic acid through catalytic decomposition of the hydroperoxides of cyclopentanone

✍ Scribed by E. K. Starostin; A. V. Aleksandrov; S. V. Shchetinin; V. V. Gushchin; G. I. Nikishin


Book ID
112444912
Publisher
Springer
Year
1989
Tongue
English
Weight
228 KB
Volume
38
Category
Article
ISSN
1573-9171

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The decomposition of organic hydroperoxi
✍ A. W. de Ruyter van Steveninck; E. C. Kooyman πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 799 KB

## Abstract The HClO~4~‐catalyzed decomposition of a number of alkylbenzyl hydroperoxides has been investigated by a study of the reaction kinetics in 50% w ethanol at 50Β°C. A Hammett relation (__p__ = ‐4.57) has been found to exist for the decomposition of ring‐substituted Ξ±,α‐dimethylbenzyl hydro