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Synthesis of 5-Arylamino-5-tert-butyl-5-hydroxy-2(5H)-furanones

โœ Scribed by V. O. Kozminykh; E. V. Bukanova; A. O. Belyaev; E. N. Kozminykh


Book ID
111577684
Publisher
Springer US
Year
2003
Tongue
English
Weight
101 KB
Volume
39
Category
Article
ISSN
0009-3122

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Convenient synthesis of 5-alkylidene-2(5
โœ R.W. Saalfrank; W. Hafner; J. Markmann; H.-J. Bestmann ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 341 KB

Starting fro enolizing 1.2~diketones 1 and (2,2dlathoxyvinylidene)triphenylphosphorane (1) or from 2 and (2.2-dlethoxyvlnyl)triphewlphosphonlu tetrafluorohorate (a) the orthoesters 2 are prepared. 9 can be hydrolyzed under acldlc conditions to glve 5-alkylldene-2(SH)-furan%es lo. Reaction of 1,2-hyd