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Convenient Synthesis of 3,4-Dichloro-5-hydroxy-2(5H)-Furanone Glycoconjugates

✍ Scribed by Gondela, Edyta; Walczak, Krzysztof Z.


Book ID
120427834
Publisher
Molecular Diversity Preservation International
Year
2011
Tongue
English
Weight
138 KB
Volume
16
Category
Article
ISSN
1420-3049

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Convenient synthesis of 5-alkylidene-2(5
✍ R.W. Saalfrank; W. Hafner; J. Markmann; H.-J. Bestmann πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 341 KB

Starting fro enolizing 1.2~diketones 1 and (2,2dlathoxyvinylidene)triphenylphosphorane (1) or from 2 and (2.2-dlethoxyvlnyl)triphewlphosphonlu tetrafluorohorate (a) the orthoesters 2 are prepared. 9 can be hydrolyzed under acldlc conditions to glve 5-alkylldene-2(SH)-furan%es lo. Reaction of 1,2-hyd