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Synthesis of [5-3H] hemimellitic acid

✍ Scribed by Michael Shimoni; Jacques Azran; Ouri Buchman

Publisher: John Wiley and Sons
Year: 1988
Tongue: French
Weight: 176 KB
Volume: 25
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580250614

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✦ Synopsis

1.2.3-Benzenetricarboxylic acid (hemimellitic acid) tritiated in position 5 has been labelled at a specific activity of 16.2 Ci/mmol, starting from 3-bromo naphthalic anhydride. Attempts at direct bromination of the acid followed by tritiodebromination, or of general labelling by hydrogen-tritium exchange gave poor results.

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