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Synthesis of 5-(2′-pyridyl)-indolizines by the reaction of 2-(2′-pyridyl)-pyridinium-ylides with activated alkynes

✍ Scribed by Ioan I. Druta; Mioara A. Andrei; Pompiliu S. Aburel

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
388 KB
Volume
54
Category
Article
ISSN
0040-4020

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The reaction of 2-(2'-pyridyl)-pyridinium N-ylides with substituted ethylenes such as acrylonitrile and ethyl acrylate gave the corresponding tetrahydroindolizine derivatives in high yields. Tetrahydroindolizine derivatives were dehydrogenated by treating with tetrapyridinecobalt(II) bichromate [CoP

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